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Question


Answer the following questions :
(i) What is meant by the chirality of compound? Give an example.

(ii) Which one of the following compounds is more easily hydrolyzed by KOH and why?
CH3CH(Cl)CH2CH3 or CH3CH2CH2Cl

(iii) Which one undergoes SN2 substitution reaction faster and why?
(compounds are shown in the above image)

502915_5942558be2304aa699453218e9057240.png

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Solution

(i) Chirality is the property of a molecule to have non-super-imposable mirror image. These molecules contain one asymmetric carbon atom. e.g., Butan - 2- ol

(ii) CH3CH(Cl)CH2CH3 is more easily hydrolyzed due to the formation of more stable secondary carbocation.

(iii) CH3CH2CH2CH2CH2I undergoes SN2 substitution reaction faster because I is a better leaving group due to its large size.

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