Aqueous CuSO4 is electrolyzed using Ag as anode and Cu as cathode, then product of electrolysis at anode and cathode are, respectively
Ag+, Ag
CuSO4→Cu2++SO2−4H2O→H++OH−Anode: SO2−4, OH−, Ag(s)Ag(s)→Ag++e−Cathode: (Cu2+, H+, Ag+) High E∘ valueAg++e−→Ag(s)