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Question

Aqueous solution of 0.004 M Na2SO4 and 0.01 M glucose are isotonic. The degree of dissociation of Na2SO4 is:

A
25%
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B
60%
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C
75%
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D
85%
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Solution

The correct option is C 75%
The degree of dissociation of NaSO4 is 75 %

For two solutions to be isotonic

πNa2SO4=πglucose

C1RT(1+2α)=C2RT

0.004×(1+2α)=0.01

α=0.75 or 75%

Hence, the correct option is C

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