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Question

Aqueous solutions of two compounds M−O−H and M′−O−H have been prepared in two different beakers. If the electronegativity of M=3.5, M′=1.72, O=3.0 and H=2.1, then the solutions respectively are:

A
acidic, acidic
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B
acidic, basic
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C
basic, basic
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D
basic, acidic
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Solution

The correct option is B acidic, basic
In the compound MOH, if ionization enthalpy or electronegativity of M is low, the compound will act as a base and if the ionization enthalpy or electronegativity of M is high, the compound will behave as an acid. Therefore, MOH will act as an acid as electronegativity of M is high (3.5) and MOH will act as a base as electronegativity of M is low (1.72).

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