1. CH3Cl > CH3Br > CH3CH2Cl > CH3 – CH(CH3) – Cl (less hindered more reactive)
2. phenol < 4 – nitrophenol < 2,4,6-trinitrophenol (electron withdrawing group, less acidic)
3. o –cresol< phenol < o – nitrophenol (CH3 is electron releasing, more acidic)
4. n – butane < etoxy –ethane < pentanal < pentanol (molecular weight increases, boiling point increases)
5. methanol < ethanol < propan-1-ol < butan-2-ol < butan-1-ol< Pentanol (molecular weight increases, boiling point increases ; branching decreases boiling point)
6. C6H5OH < CH3OH < H2O (phenoxide ion is stable due to resonance hence phenol is more acidic)