Arrange the following compounds in correct order of acidic strength.
A
HCOOH>CH3COOH>C6H5OH>C2H5−OH
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B
CH3COOH>HCOOH>C6H5OH>C2H5−OH
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C
C6H5OH>HCOOH>CH3COOH>C2H5−OH
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D
None of these
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Solution
The correct option is AHCOOH>CH3COOH>C6H5OH>C2H5−OH
Acids are more acidic than alcohols therefore both acetic acid (CH3COOH) and formic acid (HCOOH) are more acidic than ethanol (C2H5OH) and phenol (C2H5OH).
When substituent group is electron releasing then the acidity decreases. Hence acetic acid (CH3COOH) is less acidic than formic acid (HCOOH).
Phenol is more acidicthan ethanol due to resonance stabilisation of phenoxide ion (C6H5O−).
Thus the correct increasing order of acidic strength is given by C2H5OH<C6H5OH<CH3COOH<HCOOH.