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Question

Arrange the following compounds in their increasing SIR (Steric Inhibition of Resonance) effect order :

A
D < B < C < A
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B
A < B < C < D
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C
C < B < A < D
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D
D < C < B < A
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Solution

The correct option is B A < B < C < D
Bulkier the group at ortho position, more is the SIR (Steric Inhibition of Resonance) .
Since order of bulkiness :
F<Cl<Br<I
The Steric Inhibition of Resonance follows the same order
The correct option is (b)

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