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Question

Arrange the following hydrides in their increasing acid strength [CH4,H2S,PH3 and SiH4]:

A
H2S<PH3<SiH4<CH4
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B
CH4<SiH4<PH3<H2S
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C
SiH4<CH4<PH3<H2S
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D
CH4<H2S<PH3<SiH4
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Solution

The correct option is B CH4<SiH4<PH3<H2S
The increasing order of the acid strength is CH4<SiH4<PH3<H2S
In a period, the nature of hydrides changes from basic to acidic. Hence, the increasing order of acid strength is SiH4<PH3<H2S.
In a group, the acidic nature of hydrides increases.
Hence, SiH4 is more acidic than CH4

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