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Question

Arrange the following in the decreasing order of their boiling points:
CH3CH2OH,HOCH2CH2OH,CH3CH2Cl.

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Solution

Boiling point of a compound increases with increases in intermolecular forces.Here HOCH2CH2OH>CH3CH2OH>CH3CH2Cl[order of intermolecular forces]
Due to two hydroxyl groups there is strong hydrogen bonding compared to one hydroxyl group and one chloride group.
So,the order of boiling points is HOCH2CH2OH>CH3CH2OH>CH3CH2Cl

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