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Question

Arrange the following in their decreasing order of basic character.

A
III>IV>I>II
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B
I>II>III>IV
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C
IV>III>II>I
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D
II>III>I>IV
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Solution

The correct option is A III>IV>I>II
Electron donor species increase the basicity while electron withdrawing species reduces it.
(III) is the most basic due to +I effect of two Me Groups. (II) is least basic since lone pair of N is involved in resonance with two carbonyl groups.
Hence the order is:
III>IV>I>II

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