Assertion (A): When two dissimilar metals are joined across the junction and maintained at different temperature a potential difference is developed.
Seebeck Effect from electron theory: Metals contain a large number of free electrons that behave like a perfect gas and when we join two dissimilar metals at different temperature a potential difference is developed. This effect is called Seebeck effect. Electrons diffuse from metal of higher electron density to that of lower density and the resultant emf causes a flow of electrons in the circuit.
Thus, Seebeck effect is due to the imbalance in potential difference between the hot and old junctions.