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Question

Assertion :Addition of NH4OH to an aqueous solution of BaCl2 in the presence of excess NH4Cl precipitates Ba(OH)2. Reason: Ba(OH)2 is soluble in water.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is D Assertion is incorrect but Reason is correct
Addition of NH4OH to an aqueous solution of BaCl2 in the presence of excess NH4Cl do not precipitates Ba(OH)2. Because the presence of NH4Cl increases the formation of BaCl2 which is aqueous.
So assertion is incorrect.
Ba(OH)2 is insoluble in water which is precipitate.
So assertion is incorrect but Reason is correct.
Hence option D is correct.

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