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Question

Assertion :Chlorobenzene on treatment with Cl2/AlCl3 gives mainly p-dichlorobenzene. Reason: Chlorine activate the ring towards an electrophile at ortho and para positions.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is C Assertion is correct but Reason is incorrect
Chlorination of chlorobenzene with chlorine in presence of anhydrous AlCl3 gives a mixture of ortho and para isomers of dichlorobenzene.

Cl shows I effect predominant over +R effect.

Assertion is correct but Reason is incorrect

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