Assertion :Coupling of $P h \oplus N H_{2}$ with aniline is faster than with phenol. Reason: Aniline is more $- e$ donating than phenol.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Assertion is correct but Reason is incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
Coupling of $P h N^{+} H_{2}$ is an electrophilic aromatic substitution reaction, the cation is the electrophile and the activated arene is a nucleophile. Aniline is more electron-donating than phenol becasuse $O$ is more electronegative than $N$ , making it less basic (basic = ability to donate electrons).
Therefore, both assertion and reason are correct and reason is the correct explanation for assertion.

Suggest Corrections

Similar questions

Assertion (A) Ethanol is a weaker acid than phenol.
Reason (R) Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) p-nitrophenol is more acidic than phenol.
Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Assertion
If BOD level of water in reservoir is less than 5 ppm it is not polluted.

Reason
High biological oxygen demand means low activity of bacteria in water.

Join BYJU'S Learning Program

Assertion :Coupling of Ph⊕NH2 with aniline is faster than with phenol. Reason: Aniline is more −e donating than phenol.

Assertion :Coupling of $P h \oplus N H_{2}$ with aniline is faster than with phenol. Reason: Aniline is more $- e$ donating than phenol.