Assertion :n-Pentane has higher boiling point than neopentane. Reason: It is due to vander waals forces.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

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Assertion is correct but Reason is incorrect.

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Both Assertion and Reason are incorrect.

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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
Structure of n pentane $C H_{3} C H_{2} C H_{2} C H_{2} C H_{3}$ and the structure of neo pentane is $(C H_{3})_{4} C$ . They are isomeric alkanes. Branching in the alkane reduces the effective surface area of the alkane. So the vander waals forces of attraction also decreases. So consequently boiling point also decreases. So both the assertion and reason are correct. So the correct option is A.

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Similar questions

ASSERTION: n-Pentane and n-Hexane belong to a homologous series.

REASON: n-Pentane and n-Hexane belong to the same class of hydrocarbons and they differ by a - $C H_{2}$ - group.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) Order of the reaction can be zero or fractional.

Reason (R) We cannot determine order from balanced chemical equation.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

Assertion (A) Boiling points of alcohols and ethers are high.
Reason (R) They can form intermolecular hydrogen-bonding.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) Order and molecularity are same.

Reason (R) Order is determined experimentally and molecularity is the sum of the stoichimetric coeffcient of rate determining elementary step.

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