Assertion :NaCl→Na++Cl− is dissociation and not ionization. Reason: Because in an ionic solid like NaCl, an electron is essentially already fully partitioned onto the chlorine. There is no transfer of electron.
Dissociation is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into smaller particles such as atoms, ions or radicals, usually in a reversible manner.
Ionization is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons to form ions. It does not split like in dissociation reaction.
Hence, Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.