General Mechanism of Electrophilic Aromatic Substitution
Assertion :Ni...
Question
Assertion :Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene. Reason: NO2 group is a m-directing group.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution
The correct option is D Assertion is incorrect but Reason is correct
The assertion is incorrect but the reason is correct as the chlorination of nitrobenzene (not the nitration of chlorobenzene) leads to the formation of m-nitrochlorobenzene because −NO2 group deactivates the ring because it is meta directing.