Assertion :Nitrobenzene is used as a solvent in Friedel-Craft's reaction. Reason: Fusion of nitrobenzene with solid KOH gives a low yield of a mixture of o- and p-nitrophenols.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

Assertion is correct but Reason is incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Nitro-benzene is used as a solvent in Friedel-Craft's reaction because it does not interfere in the reaction.

Nitro -group strongly deactivates aromatic rings to electrophilic aromatic substitution reactions because they draw electron density away from the ring by resonance, thus destabilizing the carbocation intermediate.
Friedel-Crafts reactions are particularly sensitive to deactivating substituents and cannot occur on molecules with moderate to strong deactivating groups on them.

So both are correct but reason is not the correct explanation

Suggest Corrections

Similar questions

Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) o-nitrophenol is less soluble in water than the m- and p-isomers.
Reason (R) m and p-nitrophenols exist as associated molecules.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Assertion
If BOD level of water in reservoir is less than 5 ppm it is not polluted.

Reason
High biological oxygen demand means low activity of bacteria in water.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

ASSERTION: n-Pentane and n-Hexane belong to a homologous series.

REASON: n-Pentane and n-Hexane belong to the same class of hydrocarbons and they differ by a - $C H_{2}$ - group.

Join BYJU'S Learning Program