Assertion :Oxidation of 1-nitroaphthalene gives o-nitrophthalic acid whereas 1-aminonaphthalene on oxidation gives phthalic acid. Reason: An amino group attached to the benzene ring makes it resistant to oxidation whereas nitro group makes the benzene ring susceptible to oxidation.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Assertion is correct but Reason is incorrect

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

Both Assertion and Reason are incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is C Assertion is correct but Reason is incorrect
An amino group increases the electron density in the benzene ring to which it is attached thereby making it susceptible to oxidation. Nitro group, on the other hand, decreases the electron density in the benzene ring to which it is attached thereby making it resistant to oxidation. Instead, the other benzene ring gets oxidised giving o-nitrophthalic acid.

Suggest Corrections

Similar questions

Assertion (A) Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.
Reason (R) Lewis acid polarises the bromine molecule.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) p-nitrophenol is more acidic than phenol.
Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Read the assertion and reason carefully to mark the correct option out of the options given below:
Assertion :Sulphanilic acid exists as dipolar ion whereas p-aminobenzoic acid does not.

Reason :Carboxyl group being more acidic than

- S O_{3} H

group can easily transfer a

H^{+}

to the amino group.

Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Join BYJU'S Learning Program