Assertion :p-Nitrophenol gives more electrophilic substituted compound than m-methoxyphenol. Reason: Methoxy group shows only negative I-effect.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

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Assertion is correct but Reason is incorrect.

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Both Assertion and Reason are incorrect.

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Solution

The correct option is D Both Assertion and Reason are incorrect.
In p-nitrophenol, $- N O_{2}$ group has $- I$ effect, as a result of which electron density decreases on the benzene ring, hence reactivity towards electrophilic substitution decreases. Methoxy group show both $+ R$ (due to lone pair of electrons on $O$ ) and $- I$ effect (due to greater electronegativity of $O$ ).
$- O C H_{3}$ at meta-position shows only $- I$ effect but lesser than $- I$ effect of $- N O_{2}$ group.

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Similar questions

Assertion (A) p-nitrophenol is more acidic than phenol.
Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
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(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) All collision of reactant molecules lead to product formation.

Reason (R) Only those collisions in which molecules have correct orientation and sufficient kinetic energy lead to compound formation.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
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Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) o-nitrophenol is less soluble in water than the m- and p-isomers.
Reason (R) m and p-nitrophenols exist as associated molecules.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

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