Assertion :p-toluidine is a stronger base than m-toluene. Reason: Methyl group from m-position exerts smaller electron donating inductive (+I) effect than from p-position.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is C Assertion is correct but Reason is incorrect It is correct that P-toluidine is a stronger base than m-toluene but reason is the hyperconjugation effect of methyl group from para position increases basic strength of para isomer. Hence Reason is incorrect.