Assertion :pH value of HCl solution is less than that of acetic acid of the same concentration. Reason: In equimolar solution, the number of titrable protons present in HCl is less than that present in acetic acid.
A
both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
assertion is correct but Reason is incorrect
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D
both Assertion and Reason are incorrect
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Solution
The correct option is C assertion is correct but Reason is incorrect pH value of HCl solution is less than that of acetic acid of the same concentration. HCl is strong acid and is completely dissociated. Acetic acid is weak acid and partially dissociated. Thus, hydrogen ion concentration is higher in HCl than in acetic acid. Lower is the pH, greater is the hydrogen ion concentration and greater is the acid strength. In equimolar solution, the number of titrable protons present in HCl is equal to that present in acetic acid. Assertion is correct but Reason is incorrect