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Question

Assertion: pKa of a weak acid becomes equal to the pH of the solution at the mid-point of titration.

Reason: The molar concentration of the proton donor and proton acceptor becomes equal at the mid-point.
Read the above assertion and reason and choose the correct option regarding it.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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E
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
pH=pKa+log[salt][acid]
Therefore pH=pKa.
Reason is incorrect because at midpoint of titration of weak acid, [salt] = [Acid]
Option B is correct.

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