Assertion : RS⊝ is a stronger nucleophile and a better leaving group than RO⊝ Reason : RS⊝ is a weaker base than RO⊝
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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E
Both Assertion and Reason are incorrect
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Solution
The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion Acidity: RSH>ROH Basicity: RS⊝<RO⊝ When nucleophilic centres are different and belong to the same group, nucleophilicity is antiparallel to basicity. Nucleophilicity: RS⊝<RO⊝ Weaker the base. better is the leaving group So the leaving group ability of RS⊝<RO⊝