Assertion: Sodium chloride is added to precipitate soap after saponification.
Reason: Hydrolysis of esters of long-chain fatty acids by alkali produces soap in colloidal form.
Assertion
➢ Hydrolysis of esters of long-chain fatty acids by alkali gives the soap, which remains in colloidal form. The process is called saponification.
⮚ Precipitation of the soap is done by the addition of NaCl (sodium chloride) which is a different process.
So, assertion is correct.
Reason
Hydrolysis of esters of long-chain fatty acids by alkali produces soap, which remains in colloidal form.
Therefore, reason is also correct.
So, both assertion and reason are correct statements, and reason explains the assertion.
So correct answer is option (B)