Assertion :Tert-butyl methyl ether on treatment with HI at $100^{o} C$ gives a mixture of methyl iodide and tert-butyl alcohol. Reason: This reaction occur via $S_{N} 2$ mechanism.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Assertion is correct but Reason is incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are incorrect

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

Open in App

Solution

The correct option is D Both Assertion and Reason are incorrect
Tert-butyl methyl ether on treatment with HI 100oC gives a mixture of methyl alcohol and tert-butyl iodide. As tert butyl is a bulky group nuclephile gets hindered and ${S_{N}}^{2}$ reaction cannot take place.

As the stable tertiary carbocation formed so the $S N^{1}$ mechanism takes place and gives tertiary butyl iodide..

Suggest Corrections

Similar questions

Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) Boiling points of alcohols and ethers are high.
Reason (R) They can form intermolecular hydrogen-bonding.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion (A) Phenol forms 2, 4, 6-tribromophenol on treatment with $B r_{2}$ in carbon disulphide at 273K.
Reason (R) Bromine polarises in carbon disulphide.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Assertion – The non-fusible impurities present in iron ore are removed by $C a C O_{3}$ .

Reason: $C a C O_{3}$ which decomposes into $C a O$ and $C O_{2}$ . The $C a O$ formed reacts with $S i O_{2}$ to remove silica

Join BYJU'S Learning Program

Assertion :Tert-butyl methyl ether on treatment with HI at 100oC gives a mixture of methyl iodide and tert-butyl alcohol. Reason: This reaction occur via SN2 mechanism.

Assertion :Tert-butyl methyl ether on treatment with HI at $100^{o} C$ gives a mixture of methyl iodide and tert-butyl alcohol. Reason: This reaction occur via $S_{N} 2$ mechanism.