Assertion: The atomic weight of an element is given by Dulong Petit's law : Atomic weight × specific heat (cal /mole) = 6.4
Reason: The formula is valid for metals only and not for all elements.
A
Assertion is correct but Reason is wrong.
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B
Assertion is wrong but Reason is correct.
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C
both Assertion and Reason are correct and Reason is the correct explanation of Assertion
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D
both Assertion and Reason are correct but Reason is not the correct explanation of Assertion
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Solution
The correct option is A Assertion is correct but Reason is wrong. The correct expression for Dulong Petit's law is "molar mass (M) (g/mol) × specific heat (c) (J/g.K) = 25 J/mol. K". This equation is valid for metals and solids elements having an atomic mass more than 40 and not for all elements. Hence, Assertion is correct but Reasoning is wrong.