Assertion :The carbonate of lithium decomposes easily on heating to form lithium oxide and CO2. Reason: Lithium being very small in size polarises large carbonate ion leading to the formation of more stable Li2O and CO2.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion The carbonate of lithium decomposes easily on heating to form lithium oxide and CO2. Other alkali metal carbonates do not decompose.
Li2CO3Δ−→Li2O+CO2↑
Lithium being very small in size polarises large carbonate ion. It distorts the electron cloud on the nearby oxygen atom of large carbonate ion. It weakens C−O bond and strengthens Li−O bond. It leads to the formation of more stable Li2O and CO2.
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.