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Question

Assertion :The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different. Reason: Water is polar and benzene is non-polar.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

In benzene acetic acid dime rises but in water, it does not. This is because benzene is non-polar whereas water is polar. Hence, the number of particles becomes different in both the solvents.


Depression in freezing point is a colligative property i.e. it depends upon the number of particles in solution. Hence, molecular mass determined by depression in freezing point method comes out to be different i.e. they have different depression in freezing point.


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