Assertion :The overall order of the reaction is the sum of the exponents of all the reactants in the rate expression. Reason: There are many higher order reactions.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Both Assertion and Reason are incorrect

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Solution

The correct option is C Assertion is correct but Reason is incorrect
The overall order of the reaction is the sum of the exponents of all the reactants in the rate expression.

For example, for a reaction $m A + n B \to C$ , the overall order of the reaction is $m + n$ .

with rate law expression rate $= [A]^{m} [B]^{n}$

There are very few higher-order reactions. This is because the probability of 3 or more molecules colliding at the same time is rare.

The assertion is correct but Reason is incorrect.

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Similar questions

Assertion (A) Order and molecularity are same.

Reason (R) Order is determined experimentally and molecularity is the sum of the stoichimetric coeffcient of rate determining elementary step.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

Assertion (A) Order of the reaction can be zero or fractional.

Reason (R) We cannot determine order from balanced chemical equation.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) The enthalpy of reaction remains constant in the presence of a catalyst.

Reason (R) A catalyst participating in the reaction forms different activated complex and lowers down the activation energy but the difference in enrgy of reactant and product remains the same.

Assertion: All the points (1, 0), (-1, 0), (2, 0) and (5, 0) lie on the x – axis.
Reason: Equation of the x-axis is y = 0

Choose the correct option.

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