Assertion :The pka of acetic acid is lower than that of phenol Reason: Phenoxide ion is more resonance stabilized

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

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Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

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Assertion is correct but Reason is incorrect

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Both Assertion and Reason are incorrect

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Solution

The correct option is C Assertion is correct but Reason is incorrect
Lower the value of pKa, more acidic will be the compound. Acetic acid is more acidic than phenol. This indicates that carboxylate ion should be more stable than the phenoxide ion and it is clear that carboxylate ion has more equivalent resonating structures than the phenoxide ion.

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Similar questions

Assertion (A) p-nitrophenol is more acidic than phenol.
Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Q. Read the assertion and reason carefully to mark the correct option out of the options given below:
(a)If both assertion and reason are true and the reason is the correct explanation of the assertion.
(b)If both assertion and reason are true but reason is not the correct explanation of the assertion.
(c)If assertion is true but reason is false.
(d)If assertion is false but reason is true.

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(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
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Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc. $H N O_{3} a n d H_{2} S O_{4}$ mixture.
Reason (R) - OH group in phenol is o-,p-directing.
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(b) Assertion and reason both are wrong statements.
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