Assertion :Treatment of phenol with nitrous acid yields p-benzoquinone monoxime. Reason: p-nitrosophenol and p-benzoquinone monoxime are tautomers
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution
The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion Nitrous acid gives nitrosomine ion (NO+) which attacks phenol at less hindered p-position of form p-nitrosophenol which is a tautomer of p-benzoquinone monoxide