Assume that a drop of liquid evaporates by decrease in its surface energy, so that its temperature remain unchanged. What should be the minimum radius of the drop for this to be possible? The surface tension is T, density of liquid is ρ and L is its latent heat of vaporization.
given that,
surface tension =T
density of liquid = ρ
latent heat =L
We know that,
Decrease in surface energy = heat required in vaporization
Now,
Decrease in surface energy
=T×ΔA
=2T×(4πrdr).....(I)
Now, heat required in vaporization = latent heat
=ML
=VρL
=4πr2ρL....(II)
Now, from equation (I) and (II)
2T(4πrdr)=4πr2ρL
r=2TρL
Hence, the radius is 2TρL