Assume that there is no repulsive force between the electrons in an atom but the force between positive and negative charges is given by Coulomb's law as usual. Under such circumstance. calculate the ground state energy of a He−atom
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Solution
For H atom Z=1 and n=1 ∴En=−mge48ε2012h2=13.6eV For He- atom, Z=4 and n=1 ∴En=−mge48ε2012h2=−4×13.6=54.4eV