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Question

At 25 C, the standard oxidation potentials of Zn and Ag in water are:
Zn(s)Zn+2(aq)+2e, E0=0.76 V
and Ag(s)Ag+(aq)+e, E0=0.80 V.
Which of the following reaction actually takes place?

A
Zn2+(aq)+2Ag(s)2Ag+(aq)+Zn(s)
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B
Zn(s)+2Ag+(aq)Zn2+(aq)+2Ag(s)
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C
Zn2+(aq)+2Ag+(aq)Zn(s)+2Ag(s)
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D
Zn(s)+Ag(s)Zn2+(aq)+Ag+(aq)
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Solution

The correct option is B Zn(s)+2Ag+(aq)Zn2+(aq)+2Ag(s)
Looking at the oxidation potential values of the reaction, Zn has a higher value compared to Ag. Thus, Zn gets more easily oxidised as compared to Ag.
Ag gets reduced and Zn gets oxidised. Hence, the reactions are as follows:
Zn(s)Zn2+(aq)+2e
2Ag+(aq)+2e2Ag(s)
Overall reaction: Zn(s)+2Ag(aq)Zn2+(aq)+2Ag(s)

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