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Question

At higher pressure, which one of the following is correct about volume of the gases?

A
Vreal>Videal
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B
Vreal<Videal
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C
Vreal=Videal
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D
None of these
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Solution

The correct option is A Vreal>Videal
The kinetic theory assumes that gas particles occupy a negligible fraction of the total volume of the gas. As a result, real gases are not as compressible at high pressures as an ideal gas because we can't ignore the volume of the gas molecules. The volume of a real gas is therefore larger than expected from the ideal gas at high pressures.

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