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Question

At S.T.P. the volume of a gas is found to be 273 mL? What will be the volume of this gas at 600 mm Hg and 273C?

A
391.8 ml
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B
380 ml
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C
691.6 ml
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D
750 ml
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Solution

The correct option is A 691.6 ml
S.T.P. has T= 273 K and P=1 atm=760 mm of Hg
If V=273 mL at STP then using the relation P1V1T1=P2V2T2
And substituting $P_1=760\ mm\ Hg,\ P_2=600\ mm\ Hg,\ V_1=273\ mL,\ V_2=V\ mL,\ T_1=293\ K\ and\ T_2=273+273=546\ K$
we get:
760×273273=600×V546
V=691.6 mL
Option C is correct.

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