Dear student
i) The given chemical equation
NaOH + H2SO4 → Na2SO4 + H2O
To balance two sodium atoms on product side we assign coefficient 2 to NaOH on reactant side and two balance four Hydrogen on reactant side we assign coefficient 2 to H2O on product side.
Therefore the balanced form of the above chemical equation will be
2NaOH + H2SO4 → Na2SO4 + 2H2O
ii) The given chemical equation
MnO2 + HCl → MnCl2 + Cl2 + H2O
To balance four chlorine atoms on product side we assign a coefficient 4 to HCl and then to balance four Hydrogen on reactant side we assign a coefficient 2 to H2O on product side
Therefore the balanced form of the above chemical equation will be
MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O
Hope this answers your question.
Regards