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Question

Balance the following redox reactions by ion-electron method.

H2O2(aq)+Fe2+(aq)Fe3+(aq)+H2O(l) (in acidic solution)

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Solution

The oxidation half reaction is Fe2+(aq)Fe3+(aq)+e.

The reduction half reaction is H2O2(aq)+2H+(aq)+2e2H2O(l).

In the above half-reactions, all the atoms are balanced.

The oxidation half-reaction is multiplied by 2 so as to balance the number of electrons in oxidation half-reaction with reduction half-reaction.

2Fe2+(aq)2Fe3+(aq)+2e.

The oxidation half-reaction is then added to the reduction half-reaction to obtain a balanced chemical equation.

H2O2(aq)+2Fe2+(aq)+2H+2Fe3+(aq)+2H2O(l)

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