Benzene and toluene form nearly ideal solution At 20∘C, the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at 20∘C for a solution containing 78 g of benzene and 46 g of toluene in torr is
A
50
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B
25
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C
37.5
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D
53.5
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Solution
The correct option is A 50 According to Raoult's law, PB=P∘BXBP∘B=75 XB=7878(7878)+(4692)=11+0.5=11.5PB=75×11.5=50torr