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Question

Bleaching action of chlorine is permanent while bleaching action of sulphur dioxide is temporary, why?

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Solution

Bleaching action of SO2: Bleaching by SO2 is permanent due to the process of reduction in the presence of moisture.
SO2+2H2OH2SO4+2[H] (nascent)
Colour material +[H] Colourless air−−−− Colour
Bleaching action of Cl2: Bleaching by Cl2 is temporary due to the process of oxidation in the presence of moisture.
Cl2+H2O2HCl+[O] (nascent)
Colour material +[O] Colourless

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