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Question

By which of the following reagents, both the aldehyde and the primary alcoholic group of glucose are oxidised?

A
Tollen's reagent
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B
Br2+H2O
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C
HNO3
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D
All of these
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Solution

The correct option is C HNO3
Tollen's reagent and bromine water both are a mild oxidizing agent, thus oxidize only aldehyde group. HNO3, being a strong oxidizing agent, oxidizes both the aldehyde as well as the primary alcoholic group and gives glucaric acid.
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