C2H52CO A- A alcohol can also be obtained by-

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Nucleophilic Addition at the Carbonyl

C2H52CO A. ...

Question

${(C_{2} H_{5}))}_{2} C O H_{3} O^{+} - ----------- \to {C H}_{3} M g B r (e x c e s s) A$ . $A$ (alcohol) can also be obtained by:

{C H}_{3} {C H}_{2} C H O H_{3} O^{+} - ---------- \to {C H}_{3} M g B r (2 m o l)

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C H_{3} O | | C O C_{2} H_{5} C H_{3} M g B r (2 m o l) - ---------- \to H_{3} O^{+}

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C H_{3} O | | C C H_{3} C H_{3} M g B r (1 m o l) - ---------- \to H_{3} O^{+}

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both

B

and

C

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C H_{3} O ∥ C C H_{3}

C H_{3} O ∥ C O H

C H_{3} O ∥ C C H_{3} I_{2} / N a O H - ----- \to △, H^{+}

C H_{3} O ∥ C C H_{3} C r_{2} O_{7}^{2 -} / H^{+} - ------ \to

C H_{3} O ∥ C C H_{3} A g (N H_{3})_{2}^{+} - ----- \to

C H_{3} C H_{2} C H O

C H_{3} C | | O C H_{3}

C H_{3} \begin{matrix} O ∥ \end{matrix} C O H + C H_{3} C H_{2} 18 O H ⟶ C H_{3} \begin{matrix} O ∥ \end{matrix} C O C_{2} H_{5} + H_{2} O

P h - C H_{3} O

P h - S - C H_{3}

C H_{3} O -

C H_{3} - S -

Arrange in decreasing order of basicity,

$H_{2} O, O H^{-}, C H_{3} O H, C H_{3} O^{-}$

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