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Question

C (diamond) C (graphite), ΔS300=10 cal mol1
C (diamond) +O2CO2; ΔH=91 kcal mol1 at 300K
C (graphite) +O2CO2; ΔH=x at 300K.
x is:

A
81 kcal
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B
101 kcal
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C
94 kcal
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D
88 kcal
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Solution

The correct option is D 88 kcal
C (diamond) C (graphite), ΔS300=10 cal mol1
C(d)+O2CO2(1)ΔH=91kcalmol1
C(g)+O2CO2(1)ΔH=21300k
eqn(1)eqn(2)
ΔH(3)91x
c (diamond) (graphite)-(3)
at equilibrium ΔC=0;ΔC=ΔHTΔS
ΔH(3)=TΔS,300×10cal/mol=3kcalmol
30[21=88kcal]

1199766_1037445_ans_2ca8f5ff065d4ab68950fc5f897be03f.jpg

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