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Question

C(s)+O2(g)CO2(g),ΔH=+94.0Kcal.

CO(g)+12O2(g)CO2(g),ΔH=67.7Kcal.

From the above reactions find how much heat (Kcal mole1) would be produced in the following reaction:

C(s)+12O2(g)CO(g)

A
20.6
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B
26.3
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C
44.2
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D
161.7
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Solution

The correct option is D 161.7
The thermochemical reactions are as given below.

C(s)+O2(g)CO2(g)ΔH=+94.0Kcal. ......(1)

CO(g)+12O2(g)CO2(g),ΔH=67.7Kcal ......(2)

The reaction (2) is reversed and added to the reaction (1) to obtain the reaction C(s)+12O2(g)CO(g).

The heat produced in this reaction is 94.0(67.7)=161.7 Kcal/mole

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