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Question

C(s)+O2(g)CO2(g);ΔH=94.3 kcal/mol
CO(g)+1/2O2(g)CO2(g);ΔH=67.4 kcal/mol
O2(g)2O(g);ΔH=117.4 kcal/mol
CO(g)C(g)+O(g);ΔH=230.6 kcal/mol
Calculate ΔH for C(s) C(g) in Kcal/mol.

A
171
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B
254
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C
117
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D
145
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Solution

The correct option is D 145
C(s)+O2(g)CO2(g);ΔH=94.3 kcal/mol ......(1)
CO(g)+1/2O2(g)CO2(g);ΔH=67.4 kcal/mol ......(2)
O2(g)2O(g);ΔH=117.4 kcal/mol ......(3)
CO(g)C(g)+O(g);ΔH=230.6 kcal/mol ......(4)
ΔH for C(s) C(g) ......(5)
Add equations 1 and 4 and from the result, substract equation 2. Divide equation 3 with 2 and substract it from above result to obtain equation 5.
ΔH=94.3 kcal/mol+230.6 kcal/mol(67.4 kcal/mol)117.4 kcal/mol2
ΔH=145 kcal/mol

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