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Question

CaCO3(s)CaO(s)+CO2(g) in closed container at equilibrium. What would be the effect of addition of CaCO3 on the equilibrium concentration of CO2 :

A
Increases
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B
Decreases
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C
Data is not sufficient
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D
Remains unaffected
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Solution

The correct option is D Remains unaffected
CaCO3(s)CaO(s)+CO2(g)
K2=PCO2, therefore, Kc Konly depends upon concentration of CO2 as long as temperature remains contants and both CaCO3 and CaO(s) are present.

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