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Question

In the heterogenous equilibrium, CaCO3(s)CaO(s)+CO2(g), what would be the effect of addition of CaCO3 on the equilibrium concentration of CO2?

A
Increases
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B
Unpredictable
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C
Decreases
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D
Remains unaffected
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Solution

The correct option is D Remains unaffected
In the formula of Keq concentration of solid compounds are not included
hence for the given reaction, Keq= Concentration of CO2.
So, the concentration of CaCO3 does not effect the equilibrium concentration of CO2.

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