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Question

Calculate ΔH/kJ for the following reaction using the listed standard enthalpy of reaction data:

2N2(g)+5O2(g)2N2O5(s)

N2(g)+3O2(g)+H2(g)2HNO3(aq)ΔH/kJ=414.0

N2O5(s)+H2O(I)2HNO3(aq)ΔH/kJ=86.0

2H2(g)+O2(g)2H2O(I)ΔH/kJ=571.6

A
84.4
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B
243.6
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C
71.2
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D
121.8
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Solution

The correct option is B 84.4
For the reaction, 2N2(g)+5O2(g)2N2O5(s)

N2(g)+3O2(g)+H2(g)2HNO3(aq)ΔH/kJ=414.0

N2O5(s)+H2O(I)2HNO3(aq)ΔH/kJ=86.0

2H2(g)+O2(g)2H2O(I)ΔH/kJ=571.6

Applying Hess's law,

ΔHr=[2(414)+2(86)+571.6]

ΔHr=84.4kJ

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