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Question

Calculate magnetic moment of Mn in MnO4 x unpaired electrons on Mn in MnO4y BM.
x,y are respectively:

A
1,3
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B
2,22
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C
3,15
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D
none of these
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Solution

The correct option is A 1,3
Oxidation number of Mn in MnO4=+7it is expected that (Mn in) MnO4 sholud have [Ar] configuration and should be colourless. But one electron is transfered to Mn from oxygen and thus Mn in MnO4 has one unpaired electron making it paramagnetic.Magnetic moment =N(N+2)=3BM

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